Tag: Zero-practical-application

  • “Astatine – just say no!” The Thermal Fury of Astatine: Calculating the Heat Output of an element you’ve never heard of.

    This is a follow-on from the very awesome video by Randall Munroe on making a wall made of 1L samples (10x10x10cm) of every element in the periodic table.

    The question is ‘what exactly is the power output of astatine?’


    A solid $7\text{ kg}$ sample of Astatine-210 (the most stable isotope) would generate a thermal output of approximately $233\text{ MW}$ $(233,000,000\text{ watts})$ at the moment of its creation. If the sample consisted of Astatine-211—the isotope commonly created in particle accelerators—the thermal output would climb even higher, reaching roughly $495\text{ MW}$ $^{[1, 2]}$.

    To put this scale into perspective, a 1-litre block of astatine would produce as much heat as a small commercial nuclear reactor, entirely concentrated within a handful of matter.

    But don’t take my word for it; LET’S USE FIRST PRINCIPLES!!!.

    1. Count the Atoms

    To find out how much heat is released, we first determine how many atoms are present in a $7\text{ kg}$ ($7,000\text{ g}$) sample using Avogadro’s number:

    $$N = \frac{\text{Mass}}{\text{Molar Mass}} \times N_A$$

    Using Astatine-210 ($210\text{ g/mol}$) $^{[2]}$:

    $$N = \frac{7,000\text{ g}}{210\text{ g/mol}} \times 6.022 \times 10^{23}\text{ atoms/mol}$$

    $$\approx 2.0073 \times 10^{25}\text{ atoms}$$

    2. Determine the Decay Constant

    Next, we calculate the decay constant ($\lambda$) using the half-life of Astatine-210, which stands at $8.1\text{ hours}$ ($29,160\text{ seconds}$) $^{[3]}$:

    $$\lambda = \frac{\ln(2)}{t_{1/2}} = \frac{0.69315}{29,160\text{ s}}$$

    $$\approx 2.377 \times 10^{-5}\text{ s}^{-1}$$

    3. Calculate Total Radioactivity

    The total radioactivity, or activity ($A$), measured in Becquerels ($\text{Bq}$, decays per second) is the product of the number of atoms and the decay constant:

    $$A = \lambda \times N$$

    $$A = (2.377 \times 10^{-5}\text{ s}^{-1}) \times (2.0073 \times 10^{25})$$

    $$\approx 4.771 \times 10^{20}\text{ Bq}$$

    4. Convert Energy to Watts

    Every individual decay of Astatine-210 releases an average combined radiation energy—comprising alphas, electrons, and photons—of approximately $3.0515\text{ MeV}$. We convert this particle energy into Joules ($1\text{ MeV} = 1.6022 \times 10^{-13}\text{ J}$) $^{[3, 4]}$:

    $$\text{Energy per decay} = 3.0515\text{ MeV} \times 1.6022 \times 10^{-13}\text{ J/MeV}$$

    $$\approx 4.889 \times 10^{-13}\text{ J}$$

    Multiplying the total decays per second by the energy per decay yields the absolute power output:

    $$P = A \times \text{Energy per decay}$$

    $$P = (4.771 \times 10^{20}\text{ Bq}) \times (4.889 \times 10^{-13}\text{ J})$$

    $$\approx 2.333 \times 10^8\text{ W}$$

    5. Final Thermal Output Result

    The hypothetical initial thermal output of a solid $7\text{ kg}$ sample of Astatine-210 sits at $2.33 \times 10^8\text{ watts}$ ($233\text{ MW}$).

    For those who prefer programmatic verification, here is the Python script used to model these calculations based on specific activity and mean energy.

    # Calculate the thermal power of Astatine-210 based on # specific activity and mean energy
    #
    # Specific activity # = 6.817e16 Bq/g
    # Mass = 7000 g
    # Mean energy per decay = 0.0097 + 0.07962 + 2.96215 = # 3.05147 MeV
    
    spec_activity = 6.817e16  # Bq/g
    mass = 7000  # g
    total_activity = spec_activity * mass  # Bq
    
    mean_energy_mev = 3.05147
    energy_j = mean_energy_mev * 1.60218e-13
    
    power_w = total_activity * energy_j
    print(f"At-210 Power: {power_w:.4e} Watts")

    References

    1. Lindegren, S., Albertsson, P., Bäck, T., Jensen, H., Palm, S., & Aneheim, E. (2020). Realizing clinical trials with Astatine-211: The chemistry infrastructure. Cancer Biotherapy and Radiopharmaceuticals, 35(6), 425–436. https://doi.org/10.1089/cbr.2019.3055 Cited by: 114
    2. ChemLin. (2024). Astatine isotopes – list and properties. ChemLin Chemical Elements. https://www.chemlin.org/chemical-elements/astatine-isotopes.php
    3. MIRDSoft. (n.d.). Astatine-210 radionuclide dosimetric data sheet. Medical Internal Radiation Dose (MIRD) Specification Sheets. https://mirdsoft.org/products/MIRDspecs/MIRDspecs_pdfs/At-210.pdf
    4. BenchChem. (2026). An in-depth technical guide to the radiotoxicity and decay products of Astatine-210. BenchChem Technical Guides. https://www.benchchem.com/pdf/An_In_Depth_Technical_Guide_to_the_Radiotoxicity_and_Decay_Products_of_Astatine_210.pdf